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Task 2: For the reactions below: Write a balanced equation. Draw the reaction mechanism. Justify the species involved as nucleophiles, electrophiles, radicals, acids or bases. Justify the reaction as...

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Task 2: For the reactions below:
  • Write a balanced equation.
  • Draw the reaction mechanism.
  • Justify the species involved as nucleophiles, electrophiles, radicals, acids or bases.
  • Justify the reaction as an addition, substitution, elimination, or condensation.
  • For the substitutions and elimination reactions predict whether the reaction is likely to be SN1,SN2,E1 or E2 with a brief justification.
  1. Bromine and Propene
  2. Bromobutane with aqueous sodium hydroxide at room temperature
  3. Chlorine with methane in the presence of UV light
  4. Methanol and ethanoic acid heated under reflux with concentrated sulphuric acid.
  5. A mixture of HCN and KCN with bromoethane.
  6. 2-bromo-2methylbutane with hot ethanoilc potassium hydroxide.
  7. Ammonia with 2-bromo-2-methylpropane.
  8. Propan-2-ol heated with concentrated sulphuric acid.

Task 3:
Some reactions produce “unexpected” products due to rearrangements.
Give an example of a rearrangement, including a reaction mechanism to show how this occurs.
Task 4:
Draw and explain the energy profiles for “two “different reactions, at least one which involves a transition stage.
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Task 2: For the reactions below: Write a balanced equation. Draw the reaction mechanism. Justify the species involved as nucleophiles, electrophiles, radicals, acids or bases. Justify the reaction as an addition, substitution, elimination, or condensation. For the substitutions and elimination reactions predict whether the reaction is likely to be SN1,SN2,E1 or E2 with a brief justification. Bromine and Propene Bromobutane with aqueous sodium hydroxide at room temperature Chlorine with methane in the presence of UV light Methanol and ethanoic acid heated under reflux with concentrated sulphuric acid. A mixture of HCN and KCN with bromoethane. 2-bromo-2methylbutane with hot ethanoilc potassium hydroxide. Ammonia with 2-bromo-2-methylpropane. Propan-2-ol heated with concentrated sulphuric acid. Task 3: Some reactions produce “unexpected” products due to rearrangements. Give an example of a rearrangement, including a reaction mechanism to show how this occurs. Task 4: Draw and explain the energy profiles for “two “different reactions, at least one which involves a transition stage.

Answered Same Day Dec 21, 2021

Solution

David answered on Dec 21 2021
125 Votes
Task:2:
+ Br2
CH2Cl2
B
B
Mechanism:
B
B
B
B
-
B
B
1)
A)

Data:
Br+ is acts as an electrophile
Addition reaction

+ KOH
H2O
Mechanism:
B)
Br OH
B
HO
-
OH

HO— is a nucleophile
SN2 reaction favored because the reaction is occu
ed in presence of aq.KOH
+ Cl2
hv/light
Mechanism:
C)
CH4
CH3Cl
Cl2
hv
Cl
CH3H
Cl
CH3Cl + H
H + Cl
HCl

Note: Radicals are intermediates
Radical substitution reactions
...
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