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Redox Reactions: Sparkling Chemistry INTRODUCTION Explosives and rocket fuels are poW ired by oxidation-reduction (redo') reactions The same is eve for sParklers which are prepared primanty from...

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Redox Reactions: Sparkling Chemistry
INTRODUCTION Explosives and rocket fuels are poW ired by oxidation-reduction (redo') reactions The same is eve for sParklers which are prepared primanty from nitrates. chlorates and metals such as magnesium: Iron and aluminum, with a binder to hold them together. The nitrates and chlorates decompose in the le mat of tho flame with enough energy to throw sparks into the air Metal nitrates decompose to form nitntes at elevated temperatures or (when the nitntes are also unstable) oxides, plus nitrogen and oxygen gas. Such is the case with barium nitrate:
2 Ba(NO3)2(s) 2 BaO(s) • N2(g XXXXXXXXXXg) Potassium chlorate decomposes to yield potassium chloride and oxygen gas' 2 KCI03(s) 2 KCI XXXXXXXXXXg) The formation of the gases provides the necessary force to eject bits of powdered metal that bum in air to produce oxides:
2 Mg(s) + 02(g) --------> 2 MgO(s)
4 Al(s) + 3 OZ(g) 2 Al203(s)
4 Fe(s XXXXXXXXXXg) > 2 Fe203(s) Starch will be used as a binder in this experiment, and iron wire will serve as both a support and a conductor of heat to keep the sparklers burning.
PROCEDURE
• Weigh the following inorganic ingredients on separate weighing papers: 5.0 g iron powder (-200 mesh) 0.25 g magnesium powder (-325 mesh) 1.0 g aluminum powder XXXXXXXXXXmesh) 3.0 g potassium chlorate 12.5 g barium nitrate
• Combine all of the above in a large beaker, mix well to obtain a uniform mixture. • Weigh out 3.0 g of soluble starch in a 250 mL beaker and add 8.0 mL of distilled water.
Answered Same Day Dec 24, 2021

Solution

Robert answered on Dec 24 2021
115 Votes
Solution TTs021013_112036_8
Background:
A Sparkler is a sparkling example of Oxidation-Reduction reaction. So, let us see
what makes a sparkler.
Oxidizers: Ba(NO3)2 KCLO3
Oxidizers reduce fuels -which is an exothermic reaction. At high temperature both
the oxidizers produce oxygen gas and barium nitrate produces nitrogen gas in
addition to oxygen gas. High volume of these gases forces the burning metal
particles to eject with high speed which gives rise to “sparkling” effect.
2 Ba(NO3)2 (s) ------- 2 BaO (s) + 2 N2(g) + 5 O2(g)
2 KClO3(s) -------- 2 KCl (s) + 3 O2(g)
Fuel: Metal powder e.g. Mg, Al and Fe.
These serve as both - fuel and reducing agent. When these metals glow like
incandescent light on burning. Burning...
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