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Chemical Systems I Homework 2 Due: February 8, 2013 Homework will be graded primarily based on effort. First, please try textbook Chapter 2 problems 9, 11, 13, 25, & 26. Second, try this: • Draw, on a...

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Chemical Systems I
Homework 2
Due: February 8, 2013
Homework will be graded primarily based on effort.
First, please try textbook Chapter 2 problems 9, 11, 13, 25, & 26.
Second, try this:
• Draw, on a single diagram, your prediction of how Morse potentials would look for C-C,
C-O, and C-F bonds, showing how they would look in relation to one another. Use bond
strengths and lengths to help you decide on the relative appearance of each potential plot.
Next:
2
For this last one, just try as many as you want to gain some practice:
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Chemical Systems I Homework 2 Due: February 8, 2013 Homework will be graded primarily based on effort. First, please try textbook Chapter 2 problems 9, 11, 13, 25, & 26. Second, try this: • Draw, on a single diagram, your prediction of how Morse potentials would look for C-C, C-O, and C-F bonds, showing how they would look in relation to one another. Use bond strengths and lengths to help you decide on the relative appearance of each potential plot. Next: 1For this last one, just try as many as you want to gain some practice: 2

Answered Same Day Dec 22, 2021

Solution

David answered on Dec 22 2021
116 Votes
Solution:263191_1_CS-1-Homework-2-pdf
As bond becomes weaker, the Morse potential becomes shallower, Zero potential energy will
e higher and bond dissociation will be lower. Bond length (Internuclear distance) will also
increase in the order C – F < C – O < C– C.
Molecular potentiel energy
Intermolecular distance
C - F
C - O
C - C
ZPE
Bond dissociation energy
2.5
H HHH H
H
CH3
H
H H
H
H
H
C
H
H
H
I II
The phenyl ring in the conformation I (axial phenyl) is oriented in such a way that its interaction
with 3-H and 5-H are minimum. Of course, there may be some weak interactions between the...
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