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4. The compound pars-dichlorobenzene, often used in mothballs, is composed of 49.02% carbon, 2.743% hydrogen, and 4824% chlorine by weight. a. Deduce the empirical formula of para-dichlorobenzene. b....

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4. The compound pars-dichlorobenzene, often used in mothballs, is composed of 49.02% carbon, 2.743% hydrogen, and 4824% chlorine by weight.
a. Deduce the empirical formula of para-dichlorobenzene. b. If the molecular weight of pars-dichlorobenzene is 147.0 g what is its molecular formula?
5. When heated together, lead(11) sulphide, PbS, and lead(11) oxide, PbO, produce elemental lead and sulphur dioxide, SO,. Write a balanced equation for this reaction. Calculate the number of moles of lead that can be produced from 14.0 g of
Calculate the number of grams of SO, that can be produced from 140 g of
Answered Same Day Dec 21, 2021

Solution

Robert answered on Dec 21 2021
122 Votes
Solution.1
Step1: To calculate the empirical formula of the compound.
Element Symbol % of
element
Atomic
Mass
Moles of the
element=percentage/At.Mass
Simplest
molar ratio
Simplest
whole
no. ratio
Ca
on C 49.02 12 49.02/12 = 4.085 4.085/1.36=3 3
Hydrogen H 2.743 1 2.743/1 = 2.743 2.743/1.36=2 2
Chlorine Cl 48.24 35.5 48.24/35.5 = 1.36 1.36/1.36=1 1
So, empirical formula is C3H2Cl.
Step2.
Empirical formula mass = 12x3 + 1x2 + 35.5 = 73.5g
Given Molecular mass = 147 gmol-1
Now, n = Molecular mass/ Empirical formula mass
= 147/73.5 = 2
Molecular formula = n x Empirical formula
= 2 x C3H2Cl = C6H4Cl2
Solution2.
a) Overall reaction is
...
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