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Part A: Determine the dimensions and property of the environment (See 2D pictorial representation in the below figure). The environment of interest is the 16-acre Love Canal Landfill. The atmospheric...

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Part A: Determine the dimensions and property of the environment (See 2D pictorial
representation in the below figure). The environment of interest is the 16-acre Love Canal
Landfill. The atmospheric layer where uniform mixing is achieved can be considered to be of 1 Part A: Determine the dimensions and property of the environment (See 2D pictorial
representation in the below figure). The environment of interest is the 16-acre Love Canal
Landfill. The atmospheric layer where uniform mixing is achieved can be considered to be of 1
km depth. A surface water coverage of 1/50th (a pond) of the land surface to a depth of 20 m can
be assumed and soil covering the remaining land surface to a depth of 5 m (the depth at which
the chemical containers were buried assuming the surface underneath was sealed) can be
assumed. The sediment at the bottom of the surface water can be assumed to be of the depth of 1
cm. The concentration of suspended solids in the surface water can be assumed to be 7.4 mg/l.
Assume an average fish volume of 1 L per fish with one fish for every 100 m3 of surface water.km depth. A surface water coverage of 1/50th (a pond) of the land surface to a depth of 20 m can
be assumed and soil covering the remaining land surface to a depth of 5 m (the depth at which
the chemical containers were buried assuming the surface underneath was sealed) can be
assumed. The sediment at the bottom of the surface water can be assumed to be of the depth of 1
cm. The concentration of suspended solids in the surface water can be assumed to be 7.4 mg/l.
Assume an average fish volume of 1 L per fish with one fish for every 100 m3 of surface water.
hw-2-1-1-humnvi4p.docx hw-2supplement-1-1-13egygu5.pdf
Answered 2 days After Oct 08, 2022

Solution

Dr Shweta answered on Oct 11 2022
46 Votes
Chemical Database
    
                                                    Partition Ratios
    CAS    Chemical Name    Molar Mass    Data Temp.    Melting Point        Vapor pressure        Solubility in Water        Henry's Law Constant        logKOW        KOC        Air-Water (KAW)/Water-Air        Aerosol-Wate
Aerosol-Air        Soil-Wate
Soil-Air        Suspended Particles-Wate
Suspended Particles-Air        Sediment-Wate
Sediment-Air        Fish-Wate
Fish-Air    NOTES
            (g/mol)    °C    °C    Ref.    (Pa)    Ref.    (g/m³ or mg/L)    Ref.    (Pa·m³/mol)    Ref.        Ref.    unitless    Ref.    unitless (m³/m³)    Ref.    unitless    Ref.    unitless    Ref.    unitless    Ref.    unitless    Ref.    unitless
        Specimen Type 1    250    25    275        0.02        30        0.1666666667        2.5        130
        Specimen Type 2    250    25    -        -        -        0                        0.0000672        57.9        2.59        5.19        5.19        15.2
        Specimen Type 3    131.4    25    -        -        -        0                        15000        1010000        58000        116000        116000        226000
        Benzene    78.11    25    5.53        12700        1780        557.3016853933        2.13
        Toluene    92.13    25    -95        3800        515        679.7941747573        2.69
        Chlorobenzene    112.6    25    -45.6        1580        484        367.5785123967        2.8
        1,4-Dichlorobenzene    147.01    25    53.1        130        83        230.256626506        3.4
        Hexachlorobenzene    284.8    25    230        0.0023        0.005        131.008        5.5
        N-hexane    86.17    25    -95        20200        9.5        183224.631578947        4.11
        Tricholoroethylene    131.39    25    -73        9900        1100        1182.51        2.53
        1-Pentanol    88.149    25    -78.2        300        22000        1.2020318182        1.5
        Aniline    93.12    25    -6.3        65.19        36070        0.1682975548        0.9
        Benzo[a]pyrene    252.13    25    175        0.0000007        0.0038        0.046445        6.04
        Naphthalene    128.19    25    80.5        10.4        31        43.0056774194        3.37
        Phenanthrene    178.2    25    101        0.02        1.1        3.24        4.57
        Pyrene    202.3    25    156        0.0006        0.132        0.9195454545        5.18
        PCB-15    223.1    25    149        0.0048        0.06        17.848        5.3
        PCB-52    292    25    87        0.0049        0.03        47.6933333333        6.1
        PCB-209    498.7    25    305.9        0.0000000502        1.00E-05        2.503474        8.26
        Dibenzo-p-dioxin    184    25    123        0.055        0.865        11.6994219653        4.3
        4-chlorophenol    128.56    25    43        20        27000        0.0952296296        2.4
        Pentachlorophenol    266.34    25    190        0.00415        14        0.0789507857        5.05
        DEHP    390.54    25    -50        0.0000133        0.285        0.0182252        5.11
        p,p'-DDT    354.5    25    108.5        0.00002        0.0055        1.2890909091        6.19
        Lindane    290.85    25    112        0.00374        7.3        0.1490108219        3.7        3311
        Atrazine    215.68    25    174        0.00004        30        0.0002875733        2.75
        Hypothene    200    27.5    0        1        20        10        4        4100
        perfluorooctanesulfonic acid...
SOLUTION.PDF
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